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This review provides an overview of the fundamental principles of electrochemical energy storage in supercapacitors, highlighting various energy-storage materials and strategies for enhancing their performance, with a focus on manganese- and nickel-based materials. . Energy storage systems (ESSs) are critical for addressing efficiency, power quality, and reliability, and they are vital for contemporary power systems, particularly within the context of direct current (DC) and alternating current (AC) systems. Their charge-storage performance is largely influenced by the properties of electrode materials, electrolytes and. . Supercapacitors are among the most promising electrochemical energy-storage devices, bridging the gap between traditional capacitors and batteries in terms of power and energy density. A device that stores energy is generally called an accumulator or battery. Energy comes in multiple forms including radiation, chemical. .